Volcanic interactions with the Atmosphere

Posted by chemistlink

The most significant impacts from large explosive eruptions come from the conversion of sulfur dioxide (SO2) to sulfuric acid (H2SO4), which condenses rapidly in the stratosphere to form fine sulfate aerosols. The aerosols increase the reflection of radiation from the Sun back into space and thus cool the Earth's lower atmosphere or troposphere; however, they also absorb heat radiated up from the Earth, thereby warming the stratosphere.
Ozone depletion promoted by volcanic sulfur aerosols.
The sulfate aerosols also promote complex chemical reactions on their surfaces that alter chlorine and nitrogen chemical species in the stratosphere. This effect, together with increased stratospheric chlorine levels from chlorofluorocarbon (CFC) pollution, generates chlorine monoxide (ClO), which destroys ozone (O3). 
source: http://volcanoes.usgs.gov/hazards/gas/s02aerosols.php

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